Acridine-d9 Reactionrate kTR in Fluorene-d8D2
|
T/K
|
|
kTR/s-1
|
|
224,1
|
|
6,7
|
|
229,7
|
|
6,8
|
|
235,2
|
|
7,7
|
|
240,8
|
|
7,8
|
|
246,3
|
|
9,4
|
|
251,9
|
|
10,8
|
|
257,4
|
|
12,4
|
|
262,9
|
|
16,9
|
|
268,5
|
|
17,1
|
|
273,3
|
|
23,1
|
|
279,6
|
|
27,3
|
|
285,1
|
|
31,5
|
|
289,8
|
|
35,2
|
|
291,8
|
|
48,1
|
|
298,0
|
|
62,7
|
kTR(T)
= k(T) - k(T = 0) - kTG(T) with
k(T = 0) = kTR(T
= 0) + kTG(T =
0) = 13.58 s-1
(ODMR data point at 1.5 K) and
kTG(T)
= 28.75 s-1exp(-501.5 K/T) (Obtained from
acridine-d9 in
fluorene-d8D2
data below 200 K where photochemical contributions can be neglected.)
Download data file. View data plot.
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